Negative cooperativity upon hydrogen bond-stabilized O2 adsorption in a redox-active metal–organic framework
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چکیده
منابع مشابه
Strong Short‐Range Cooperativity in Hydrogen‐Bond Chains
Chains of hydrogen bonds such as those found in water and proteins are often presumed to be more stable than the sum of the individual H bonds. However, the energetics of cooperativity are complicated by solvent effects and the dynamics of intermolecular interactions, meaning that information on cooperativity typically is derived from theory or indirect structural data. Herein, we present direc...
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2020
ISSN: 2041-1723
DOI: 10.1038/s41467-020-16897-z